If you ever need to change the order status from php here is how to do it.
[php]
$order = new WC_Order($order_id);
if (!empty($order)) {
$order->update_status( 'completed' );
}
[/php]
Possible values: processing, on-hold, cancelled, completed
This is from woocommerce/includes/abstracts/abstract-wc-order.php
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